Materials development

Low-cost, Highly Dispersive Multilayer Graphene

Overview

Graphene, a sheet-shaped nanocarbon, is said to have various properties, such as thermal conductivity, lubricity, strength, electromagnetic wave absorption, and electrical conductivity. Since it has often been produced in small volumes, taking a large amount of time, a low-cost and simple manufacturing method was desired.
Osaka Gas has had success in easily producing multilayer graphene by exfoliating graphite in a single step in water without chemical modification.


Production Process and Characteristics of Multilayer Graphene


Fig. 1. Production Process and Characteristics of Multilayer Graphene


The graphite is exfoliated in water to create graphene in a single step, which is simple and does not damage the graphene structure. In addition, it can be supplied as (1) an aqueous dispersion that is easily dispersed in water-based paints or (2) a powder that is easily dispersed in resin, rubber, oil, solvents, and water.

Fabricated Multilayer Graphene

The produced multilayer graphene is a very thin material with a thickness of 1 to 10 nm.

Therefore, by adding a large number of sheets with a small weight, it is possible to impart the beneficial physical properties of carbon, such as thermal conductivity, lubricity, and the capacity to improve the strength of rubber and plastics.


In particular, the following physical properties are notable.

1)Thermal conductivity/heat dissipation: High thermal conductivity and emissivity for quick heat transfer and heat dissipation.

2)Lubricity: Reduces friction and wear with a small added amount.

3)Strength: Improves the strength of a wide variety of materials, from thermoplastics and rubbers to inorganics.

4)Electromagnetic wave absorption: Multilayer graphene is also capable of absorbing electromagnetic waves without reflecting them.


Fig. 2. Electron micrograph of multilayer graphene

Physical property 1: Thermal conductivity/heat dissipation

・Multilayer graphene with very high thermal conductivity has the potential of increasing thermal conductivity by a factor of several tens to several hundreds.
・It improves heat dissipation by means of thermal emission.
・Because of its good dispersibility, multilayer graphene maintains the strength of plastics and the painting properties of paint.


Fig. 3. Thermal conductivity of epoxy resin with 50 wt% multilayer graphene added


Fig. 4. Added amount of multilayer graphene versus thermal conductivity


Fig. 5. Effects of adding multilayer graphene to 50 wt% alumina system


Fig. 6. Heat dissipation effect of thermal emissions by multilayer graphene


Figure 7. Heat dissipation effect by heat conduction and emission

Physical property 2: Lubricity (friction/wear reduction)

A small added amount is effective in reducing friction and wear.



Fig. 8. Friction force due to multilayer graphene-added grease



Fig. 9. Amount of wear due to multilayer graphene-added grease



Fig. 10. Friction coefficient due to multilayer graphene-added oil (SRV: vibratory friction and wear test)



Fig. 11. Amount of wear due to multilayer graphene-added oil (Shell four-ball test: wear)



Fig. 12. Friction resistance test of elastomer



Fig. 13. Comparison of amounts of wear of elastomer

Physical property 3: Strength (reinforcement of plastics/rubber)

・ A small added amount is effective in improving strength and modulus of elasticity.

・ Multilayer graphene has relatively little effect on elongation, impact strength, and tear strength.

・ Improves hardness and wear resistance.



Fig. 14. Tensile strength test of multilayer graphene-added elastomer (rendered image)



Fig. 15. Initial tensile stress of SBR with a small added amount of multilayer graphene

Physical property 4: Electromagnetic wave absorption characteristics

・ Multilayer graphene can both absorb and reflect electromagnetic waves.
・ Several styles of usage are available to choose from for specific applications, such as adding to paint and adding to resin, as well as spraying on and impregnating into non-woven fabric or paper.


Fig. 16. Electromagnetic wave absorption characteristics

Forms of Supply and Use

In addition to being dispersed in thermoplastics and thermosetting resin, multilayer graphene can also be added to paints, adsorbed to fibers, and added to oils and greases.

In particular for water-based paint, an aqueous dispersion can be used, which can reduce the effort required for dispersion.



Fig. 17. Forms of supply and use



Fig. 18. Example of addition to existing paint

Future Development

We will develop multilayer graphene suitable for specific uses, such as in composite materials and energy field, etc., and, we will promote mass production to help achieve energy saving and CO2 emissions reduction, safety, and durability improvement.

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